1. Modeling the Formation of Molybdenum Oxides from Alkoxides: Crystal Structures of [Mo(4)O(4)Cl(4)(&mgr;(2)-OEt)(4)(HOEt)(2)(&mgr;(3)-O)(2)] and [PPN](+)[Et(3)NH](+)[Cl(2)(O)Mo(&mgr;(2)-O)(2)Mo(O)Cl(2)](2)(-)
Christian Limberg, Anthony J. Downs, Alexander J. Blake, Simon Parsons Inorg Chem. 1996 Jul 17;35(15):4439-4448. doi: 10.1021/ic951468j.
The reactions of the binuclear oxomolybdenum(V) complex [Cl(2)(O)Mo(&mgr;-OEt)(2)(&mgr;-HOEt)Mo(O)Cl(2)] (1) with Me(3)Si(allyl) and SbF(3) produce the compounds [Mo(6)O(6)Cl(6)(&mgr;(3)-O)(2)(&mgr;(2)-OEt)(6)(&mgr;(2)-Cl)(2)] (2) and [Mo(8)O(8)Cl(6)(&mgr;(3)-O)(4)(OH)(2)(&mgr;(2)-OH)(4)(&mgr;(2)-OEt)(4)(HOEt)(4)] (3), respectively. Treatment of 1 with the Lewis base PMe(3) affords the tetrameric complex [Mo(4)O(4)Cl(4)(&mgr;(2)-OEt)(4)(HOEt)(2)(&mgr;(3)-O)(2)] (4), which represents another link in the chain of clusters produced by the reactions of 1 and simulating the build-up of polymeric molybdenum oxides by sol-gel methods. The crystal structure of 4 has been determined [C(12)H(32)Cl(4)Mo(4)O(12), triclinic, P&onemacr;, a = 7.376(2) Å, b = 8.807(3) Å, c = 11.467(4) Å, alpha = 109.61(1) degrees, beta = 92.12(3) degrees, gamma = 103.75(2) degrees, Z = 1]. By contrast, reaction of 1 with the nitrogen base NEt(3), followed by treatment with [PPN]Cl.2H(2)O ([PPN](+) = [Ph(3)P=N=PPh(3)](+)), gives the complex [PPN](+)[Et(3)NH](+)[Cl(2)(O)Mo(&mgr;(2)-O)(2)Mo(O)Cl(2)](2)(-) (6) in 90% yield. Its crystal structure [C(36)H(30)Cl(4)MoNOP(2), triclinic, Pna2(1), a = 21.470(6) Å, b = 16.765(2) Å, c = 9.6155(14) Å, alpha = 90 degrees, beta = 90 degrees, gamma = 90 degrees, Z = 16] includes the anion [Cl(2)(O)Mo(&mgr;(2)-O)(2)Mo(O)Cl(2)](2)(-), which is a charged derivative of the species forming the gels in sol-gel processes starting from chloromolybdenum ethoxides. Furthermore, compound 1 is found to be catalytically active in esterification and dehydration reactions of alcohols.
2. Binding of ligands containing carbonyl and phenol groups to iron(iii): new Fe6, Fe10 and Fe12 coordination clusters
Alexandros A Kitos, Constantina Papatriantafyllopoulou, Anastasios J Tasiopoulos, Spyros P Perlepes, Albert Escuer, Vassilios Nastopoulos Dalton Trans. 2017 Mar 7;46(10):3240-3251. doi: 10.1039/c6dt04830g.
The initial use of ligands 2'-hydroxyacetophenone (HL1), 2-hydroxybenzophenone (HL2) and 2,2'-dihydroxybenzophenone (H2L3) in iron(iii) chemistry is described. The syntheses and crystal structures are reported for five iron(iii) clusters: [Fe10O4(OMe)14(L1)6(MeOH)2](NO3)2·3MeOH (1·3MeOH), [Fe12O4(OH)(OMe)17(L1)8](ClO4)2·2H2O (2·2H2O), [Fe10O4(OMe)14Cl4(L2)4(MeOH)2] (3), [Fe10O4(OMe)14(L2)6(py)2](ClO4)2·MeOH (4·MeOH), where py = pyridine, and [Fe6O2(OEt)6(O2CMe)2(L3)2(HL3)2] (5). The molecular structures of the decanuclear clusters 1, 3 and 4 are organized around a {Fe10(μ4-O)4(μ3-OMe)2(μ-OMe)12}8+ core consisting of ten {Fe3O4} face-sharing defective cubane units. The core of 2 consists of a {Fe12(μ4-O)4(μ3-OMe)4(μ-OH)(μ-OMe)13}10+ unit composed of twelve {Fe3O4} face-sharing defective cubanes. The ligands (L1)- and (L2)- in 1-4 adopt the O,O'-bidentate chelating coordination mode and their roles are to terminate the further aggregation of the FeIII/O2-/RO- cores. Complex 5 contains the {Fe6(μ4-O)2(μ-OEt)6(μ-Ocarbonyl)2}4+ core, where the μ-Ocarbonyl atoms are the bridging carbonyl oxygens of the two η1:η2:η1:μ (L3)2- ligands; the (HL3)- groups behave as Ophenolate, Ocarbonyl-bidentate chelating ligands with the neutral hydroxyl group being unbound to the FeIII atoms. The core is composed of four {Fe3O4} face-sharing defective cubanes. The FeIII atoms in 1-5 are all six-coordinate with distorted octahedral geometries. The IR spectra of the complexes are discussed in terms of the known coordination modes of the ligands and the ionic character of nitrates and perchlorates. Variable-temperature magnetic susceptibility and variable-field magnetization measurements establish that 2, 3 and 5 have S = 3, 0 and 5 ground states, respectively. The susceptibility data for 5 were fitted using a 3-J model indicating the simultaneous presence of both antiferromagnetic and ferromagnetic FeIIIFeIII exchange interactions. Known magnetostructural correlations in oxido-bridged iron(iii) systems have been applied to rationalise the magnetic behaviour of the three clusters. The results of the present study demonstrate the utility of HL1, HL2 and H2L3 in the stabilisation of robust iron(iii)/oxido/alkoxido clusters.
3. Heteronuclear Dirhodium-Gold Anionic Complexes: Polymeric Chains and Discrete Units
Estefania Fernandez-Bartolome, et al. Polymers (Basel). 2020 Aug 19;12(9):1868. doi: 10.3390/polym12091868.
In this article, we report on the synthesis and characterization of the tetracarboxylatodirhodium(II) complexes [Rh2(μ-O2CCH2OMe)4(THF)2] (1) and [Rh2(μ-O2CC6H4-p-CMe3)4(OH2)2] (2) by metathesis reaction of [Rh2(μ-O2CMe)4] with the corresponding ligand acting also as the reaction solvent. The reaction of the corresponding tetracarboxylato precursor, [Rh2(μ-O2CR)4], with PPh4[Au(CN)2] at room temperature, yielded the one-dimensional polymers (PPh4)n[Rh2(μ-O2CR)4Au(CN)2]n (R = Me (3), CH2OMe (4), CH2OEt (5)) and the non-polymeric compounds (PPh4)2{Rh2(μ-O2CR)4[Au(CN)2]2} (R = CMe3 (6), C6H4-p-CMe3 (7)). The structural characterization of 1, 3·2CH2Cl2, 4·3CH2Cl2, 5, 6, and 7·2OCMe2 is also provided with a detailed description of their crystal structures and intermolecular interactions. The polymeric compounds 3·2CH2Cl2, 4·3CH2Cl2, and 5 show wavy chains with Rh-Au-Rh and Rh-N-C angles in the ranges 177.18°-178.69° and 163.0°-170.4°, respectively. A comparative study with related rhodium-silver complexes previously reported indicates no significant influence of the gold or silver atoms in the solid-state arrangement of these kinds of complexes.
