Boc-D-Leucinol
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Boc-D-Leucinol

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Category
Amino Alcohol
Catalog number
BAT-002592
CAS number
106930-51-2
Molecular Formula
C11H23NO3
Molecular Weight
217.31
Boc-D-Leucinol
IUPAC Name
tert-butyl N-[(2R)-1-hydroxy-4-methylpentan-2-yl]carbamate
Synonyms
Boc-D-Leu-ol; N-BOC-D-Leucinol; (R)-tert-Butyl (1-hydroxy-4-methylpentan-2-yl)carbamate
Appearance
Light yellowish liquid
Purity
≥ 97% (HPLC)
Density
0.984 g/mL
Boiling Point
213 °C
Storage
Store at 2-8 °C
InChI
InChI=1S/C11H23NO3/c1-8(2)6-9(7-13)12-10(14)15-11(3,4)5/h8-9,13H,6-7H2,1-5H3,(H,12,14)/t9-/m1/s1
InChI Key
LQTMEOSBXTVYRM-SECBINFHSA-N
Canonical SMILES
CC(C)CC(CO)NC(=O)OC(C)(C)C
1.Synthesis of the C-13 side chain precursors of the 9-dihydrotaxane analogue ABT-271.
Leanna MR1, DeMattei JA, Li W, Nichols PJ, Rasmussen M, Morton HE. Org Lett. 2000 Nov 16;2(23):3627-30.
N-Boc-L-Leucinol was converted to two C-13 side chain precursors of the 9-dihydrotaxane analogue ABT-271. The trans-oxazolidine acid 4 and the cis-Boc-lactam 2b were prepared in 44% and 40% overall yield, respectively, and with excellent (>98%) stereochemical purity.
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