CAS 106930-51-2 Boc-D-Leucinol - Amino Acid / BOC Sciences

Boc-D-Leucinol (BAT-002592)

* For research use only

Category

Amino Alcohol

Catalog number

BAT-002592

CAS number

106930-51-2

Molecular Formula

C11H23NO3

Molecular Weight

217.31

Specification
Reference Reading

Synonyms
Synonyms	Boc-D-Leu-ol; N-BOC-D-Leucinol; (R)-tert-Butyl (1-hydroxy-4-methylpentan-2-yl)carbamate
Appearance
Appearance	Light yellowish liquid
Purity
Purity	≥ 97% (HPLC)
Density
Density	0.984 g/mL
Boiling Point
Boiling Point	213 °C
Storage
Storage	Store at 2-8 °C
InChI
InChI	InChI=1S/C11H23NO3/c1-8(2)6-9(7-13)12-10(14)15-11(3,4)5/h8-9,13H,6-7H2,1-5H3,(H,12,14)/t9-/m1/s1
InChI Key
InChI Key	LQTMEOSBXTVYRM-SECBINFHSA-N
Canonical SMILES
Canonical SMILES	CC(C)CC(CO)NC(=O)OC(C)(C)C

1.Synthesis of the C-13 side chain precursors of the 9-dihydrotaxane analogue ABT-271.

Leanna MR1, DeMattei JA, Li W, Nichols PJ, Rasmussen M, Morton HE. Org Lett. 2000 Nov 16;2(23):3627-30.

N-Boc-L-Leucinol was converted to two C-13 side chain precursors of the 9-dihydrotaxane analogue ABT-271. The trans-oxazolidine acid 4 and the cis-Boc-lactam 2b were prepared in 44% and 40% overall yield, respectively, and with excellent (>98%) stereochemical purity.

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