D-Isoleucine (BAT-003494)
* For research use only

Category
D-Amino Acids
Catalog number
BAT-003494
CAS number
319-78-8
Molecular Formula
C6H13NO2
Molecular Weight
131.20
D-Isoleucine
Synonyms
D-Ile-OH; (2R, 3R)-2-Amino-3-methylpentanoic acid; (2R,3R)-2-Amino-3-methylvaleric acid
Appearance
White powder
Purity
≥ 98% (HPLC, Chiral purity)
Density
1.172 g/cm3(estimate)
Melting Point
272-274ºC
Boiling Point
225.8±23.0 °C(Predicted)
Storage
Store at 2-8 °C
1.Ambient-Temperature Ortho C-H Arylation of Benzoic Acids with Aryl Iodides with Ligand-Supported Palladium Catalyst.
Zhu C1, Zhang Y1, Kan J1, Zhao H1, Su W1. Org Lett. 2015 Jul 17;17(14):3418-21. doi: 10.1021/acs.orglett.5b01398. Epub 2015 Jul 2.
The ambient-temperature ortho C-H arylation of electron-deficient benzoic acids with aryl iodides has been achieved by using an Ac-Ile-OH-supported Pd catalyst. A wide range of unactivated benzoic acids could cross-couple an array of aryl iodides in moderate to excellent yields. The choice of HFIP as a solvent is crucial to realizing the mild C-H arylation, and the beneficial effect of the ligand on the reaction likely stems from the accelerated C-H activation process and the improved catalyst lifetime.
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