Fmoc-N-methyl-O-tert-butyl-L-threonine
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Fmoc-N-methyl-O-tert-butyl-L-threonine

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(2S,3R)-2-((((9H-Fluoren-9-yl)methoxy)carbonyl)(methyl)amino)-3-(tert-butoxy)butanoic acid is a Threonine derivative that has been used for the preparation of antifungal cyclic depsipeptide petriellin.

Category
Fmoc-Amino Acids
Catalog number
BAT-003793
CAS number
117106-20-4
Molecular Formula
C24H29NO5
Molecular Weight
411.50
Fmoc-N-methyl-O-tert-butyl-L-threonine
IUPAC Name
(2S,3R)-2-[9H-fluoren-9-ylmethoxycarbonyl(methyl)amino]-3-[(2-methylpropan-2-yl)oxy]butanoic acid
Synonyms
Fmoc-N-Me-L-Thr(tBu)-OH; (2S,3R)-2-[9H-fluoren-9-ylmethoxycarbonyl(methyl)amino]-3-[(2-methylpropan-2-yl)oxy]butanoic acid; Fmoc-N-methyl-O-tert-butyl-L-threonine; N-Fmoc-N-Methyl-O-tert-butyl-L-threonine; (2S,3R)-2-((((9H-Fluoren-9-yl)methoxy)carbonyl)(methyl)amino)-3-(tert-butoxy)butanoic acid
Appearance
White to light yellow powder
Purity
≥ 99% (HPLC)
Density
1.185±0.06 g/cm3
Melting Point
220-225 °C
Boiling Point
562.4±50.0 °C
Storage
Store at -20 °C
InChI
InChI=1S/C24H29NO5/c1-15(30-24(2,3)4)21(22(26)27)25(5)23(28)29-14-20-18-12-8-6-10-16(18)17-11-7-9-13-19(17)20/h6-13,15,20-21H,14H2,1-5H3,(H,26,27)/t15-,21+/m1/s1
InChI Key
VIUVLZHFMIFLHU-VFNWGFHPSA-N
Canonical SMILES
CC(C(C(=O)O)N(C)C(=O)OCC1C2=CC=CC=C2C3=CC=CC=C13)OC(C)(C)C
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