N-α-(9-Fluorenylmethoxycarbonyl)-N-ε-{2-[(t-butoxycarbonyl)amino]benzoyl}-L-lysine
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N-α-(9-Fluorenylmethoxycarbonyl)-N-ε-{2-[(t-butoxycarbonyl)amino]benzoyl}-L-lysine

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Building block for the preparation of fluorescent labelled peptides. The anthranilic acid attached at the side-chain of lysine is highly sensitive and its fluorescence spectrum does not overlap with those of Trp, Phe, and Tyr.

Category
BOC-Amino Acids
Catalog number
BAT-005461
CAS number
159322-59-5
Molecular Formula
C33H37N3O7
Molecular Weight
587.67
N-α-(9-Fluorenylmethoxycarbonyl)-N-ε-{2-[(t-butoxycarbonyl)amino]benzoyl}-L-lysine
IUPAC Name
(2S)-2-(9H-fluoren-9-ylmethoxycarbonylamino)-6-[[2-[(2-methylpropan-2-yl)oxycarbonylamino]benzoyl]amino]hexanoic acid
Synonyms
Fmoc-Lys(retro-Abz-Boc)-OH; N6-[2-[[(1,1-Dimethylethoxy)carbonyl]amino]benzoyl]-N2-[(9H-fluoren-9-ylmethoxy)carbonyl]-L-lysine; Nα-Fmoc-Nε-(Boc-2-aminobenzoyl)-L-lysine; Fmoc-ablysin(Boc)-OH; Boc-2-Abz-(Fmoc-Lys-OH)
Appearance
Off-white solid or white powder
Purity
≥ 99% (Chiral HPLC)
Storage
Store at 2-8 °C
InChI
InChI=1S/C33H37N3O7/c1-33(2,3)43-32(41)35-27-17-9-8-16-25(27)29(37)34-19-11-10-18-28(30(38)39)36-31(40)42-20-26-23-14-6-4-12-21(23)22-13-5-7-15-24(22)26/h4-9,12-17,26,28H,10-11,18-20H2,1-3H3,(H,34,37)(H,35,41)(H,36,40)(H,38,39)/t28-/m0/s1
InChI Key
SUROGAFZBBJCBX-NDEPHWFRSA-N
Canonical SMILES
CC(C)(C)OC(=O)NC1=CC=CC=C1C(=O)NCCCCC(C(=O)O)NC(=O)OCC2C3=CC=CC=C3C4=CC=CC=C24
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