Nim-Trityl-L-histidine methyl ester hydrochloride
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Nim-Trityl-L-histidine methyl ester hydrochloride

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H-His(Trt)-OMe Hydrochloride is used to prepare Nα-methyl-Nα-(nitrobenzenesulfonyl)amino acids and their incorporation into dipeptides. It is also used to synthesize azaproline-based peptide analogs of TRH.

Category
L-Amino Acids
Catalog number
BAT-004066
CAS number
32946-56-8
Molecular Formula
C26H25N3O2·HCl
Molecular Weight
448.00
Nim-Trityl-L-histidine methyl ester hydrochloride
IUPAC Name
methyl (2S)-2-amino-3-(1-tritylimidazol-4-yl)propanoate;hydrochloride
Synonyms
L-His(Trt)-OMe HCl; methyl(2S)-2-amino-3-(1-tritylimidazol-4-yl)propanoate hydrochloride; H-His(Trt)-OMe
Appearance
White to off-white powder
Purity
≥ 99.5% (HPLC)
Melting Point
142-150 °C
Storage
Store at 2-8 °C
InChI
InChI=1S/C26H25N3O2.ClH/c1-31-25(30)24(27)17-23-18-29(19-28-23)26(20-11-5-2-6-12-20,21-13-7-3-8-14-21)22-15-9-4-10-16-22;/h2-16,18-19,24H,17,27H2,1H3;1H/t24-;/m0./s1
InChI Key
RSIWDQDVADNDKT-JIDHJSLPSA-N
Canonical SMILES
COC(=O)C(CC1=CN(C=N1)C(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4)N.Cl
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