Z-1,2-cis-ACHeC-OH
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Z-1,2-cis-ACHeC-OH

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Category
CBZ-Amino Acids
Catalog number
BAT-001109
CAS number
124753-65-7
Molecular Formula
C15H17NO4
Molecular Weight
275.3
Z-1,2-cis-ACHeC-OH
Synonyms
cis-1-(Benzyloxycarbonyl-amino)-cyclohex-4-enyl-2-carboxylic acid
Appearance
White crystalline powder
Purity
≥ 99% (HPLC)
Melting Point
118-124 °C
Boiling Point
488.7ºC at 760mmHg
Storage
Store at 2-8 °C
InChI
InChI=1S/C15H17NO4/c17-14(18)12-8-4-5-9-13(12)16-15(19)20-10-11-6-2-1-3-7-11/h1-7,12-13H,8-10H2,(H,16,19)(H,17,18)/t12-,13+/m1/s1
InChI Key
QIAAZWPFGHTXNZ-OLZOCXBDSA-N
Canonical SMILES
C1C=CCC(C1C(=O)O)NC(=O)OCC2=CC=CC=C2
1.Trifluoroacetic acid catalyzed highly regioselective bromocyclization of styrene-type carboxylic acid.
Chen T1, Yeung YY2. Org Biomol Chem. 2016 Apr 29. [Epub ahead of print]
A trifluoroacetic acid catalyzed highly 6-endo regioselective bromocyclization of styrene-type carboxylic acid has been developed. The resulting 3,4-dihydroisocoumarines are valuable building blocks in organic synthesis.
2.Enantioselective CuH-Catalyzed Reductive Coupling of Aryl Alkenes and Activated Carboxylic Acids.
Bandar JS1, Ascic E1, Buchwald SL1. J Am Chem Soc. 2016 Apr 29. [Epub ahead of print]
A new method for the enantioselective reductive coupling of aryl alkenes with activated carboxylic acid derivatives via copper hydride catalysis is described. Dual catalytic cycles are proposed, with a relatively fast enantioselective hydroacylation cycle followed by a slower diastereoselective ketone reduction cycle. Symmetrical aryl carboxyclic anhydrides provide access to enantioenriched α-substituted ketones or alcohols with excellent stereoselectivity and functional group tolerance.
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